An simple option which is often overlooked in revit is to use a basic wall style.
How to make a curved glass roof in revit.
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Pick the curtain wall system and edit it s element properties.
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Here is a basic curtain wall with the system panel glazed making it faceted around the curve.
You may have to adjust its xyz location before finishing the mass which can be accomplished in plan or elevation.
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Start by creating a basic wall style which has a single layer 6mm thick and set the material to glass.
Create a simple curved roof using the roof by extrusion tool in revit.
How to do a curved glass roof with mullions.